Here, the authors report an orthogonal modification of cysteine residues using alkyl thianthreium salts, which proceeds with excellent chemoselectivity and compatibility under mild conditions ...

A key advantage of this intramolecular process is its superior chemoselectivity and stereoselectivity compared to traditional intermolecular reactions. A prime example is our nickel(0)/N-heterocyclic ...

Institute of Pharmaceutical Sciences, University of Freiburg, Albertstr. 25, 79104 Freiburg, Germany ...